Tris[2-(benzyl­imino­meth­yl)phenolato-κ2 N,O]iron(III)

نویسندگان

  • Hai-Bin Gong
  • Lei Wang
  • Wei-Tao Zhao
چکیده

In the title compound, [Fe(C(14)H(12)NO)(3)], the Fe(III) atom has a slightly distorted octa-hedral geometry and is coordinated by three Schiff base ligands, viz. 2-(benzyl-imino-methyl)-phenolate. The crystal structure is stabilized by intra-molecular C-H⋯O and C-H⋯N hydrogen bonds.

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In the title compound, [Nd(NCS)(3)(C(15)H(15)NO(2))(3)], the Nd(III) ion is coordinated by three thio-cyanate anions [Nd-N = 2.489 (8)-2.530 (7) Å] and six O atoms [Nd-O = 2.375 (4)-2.843 (5) Å] from three zwitterionic 2-meth-oxy-6-(4-methyl-phenyl-iminiometh-yl)phenolate ligands in a tricapped trigonal-prismatic geometry. Intra-molecular N-H⋯O hydrogen bonds occur. The crystal packing exhibits...

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008